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两种处理方式对测量土壤重金属元素含量结果的影响

The Influence of Two Digestion Methods on Measuring the Content of Heavy Metal in Soil

  • 摘要: 为探讨不同处理方式对土壤中重金属含量测量结果的影响,本实验通过湿法消解和高压密封消解两种处理方法消解四川盆地标准土壤(GSS-14),利用原子吸收法测定标准土壤消解液中镉(Cd)、铅(Pb)、铜(Cu)和铬(Cr)含量。结果表明:(1)采用两种消解方法均能将土壤样品中的Cd、Pb、Cu和Cr重金属元素消解出来,样品检出线均低于0.05 μg·l-1;(2)高压密封消解法消解效果优于湿法消解,从试验结果看出,高压密封法测定结果的精密度和准确度相对湿法消解较高,测定结果准确可靠;(3)高压密封消解法可有效控制样品的损失及污染,且前处理操作过程较湿法消解简单、省时、省力,称样量和酸用量较少,环境污染小,能够满足土壤检测分析的要求,因此该法可以作为一种可行的土壤重金属元素分析方法。

     

    Abstract: In order to explore the influences of the different digestion methods on measuring the content of heavy metal in soil,in this experiment,two different digestion methods,the wet-digestion and high pressure sealed digestion methods,were used to measure the content of Cd,Pb,Cu and Cr in the standard soil of Sichuan Basin by adopting atomic absorption spectrometry.The result showed that (1) the wet digestion and the high pressure sealed digestion methods were able to digest Cd,Pb,Cu and Cr.The sample detection was all below 0.05 μg·l-1; (2) The effect of the high pressure sealed digestion methods was better than that of the wet digestion method,and the relative standard deviation or accuracy of high pressure hydrothermal decomposition was more trustful than that of the wet digestion; (3) the high pressure sealed digestion method was effectively able to control the sample loss and more simple,time-saving,even to reduce the using of acid and environmental pollution.Thus the high pressure hydrothermal decomposition method would be used as a practicable method of analyzing the content of heavy metal in soil.

     

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